Many engineering applications require high surface hardness to resist wear, while complex service conditions demand adequate core strength and toughness to withstand impact and cyclic loading.
To obtain this combination of properties, two general approaches are commonly used:
- Method 1: Chemical Modification. Diffusing elements into the surface (Carburizing, Nitriding, Cyaniding).
- Method 2: Localized Heating. Hardening only the surface via rapid heating/quenching (Flame, Induction).
1. Carburizing: The Industry Standard
Carburizing is a thermochemical process where carbon is diffused into the surface of low-carbon steel (typically <0.30% C) by heating it in a carbon-rich environment. The result is a high-carbon surface that becomes hard after quenching, while the core remains tough.
The Three Common Methods:
- Gas Carburizing: Uses a controlled atmosphere (methane/propane). Most common for mass production.
- Liquid Carburizing: Uses molten cyanide salts. Fast, but involves hazardous chemicals.
- Pack Carburizing: Parts are sealed in a box with charcoal. Slower, but requires less equipment.
2. Nitriding: Distortion Control
Nitriding heats steel (900°F – 1150°F) in an ammonia atmosphere. Unlike carburizing, it does not require quenching to harden.
Because no quenching is involved, Nitriding produces minimal distortion. Parts can often be machined to final dimensions before treatment.
3. Cyaniding & Carbonitriding
Cyaniding heats parts in molten salt to diffuse both carbon and nitrogen. It produces a thin, hard case ideal for screws and nuts.
Carbonitriding is similar but uses a gaseous atmosphere (ammonia + hydrocarbons). It is often preferred over cyaniding because it avoids liquid cyanide waste disposal issues.
4. Flame & Induction Hardening
These methods do not change chemical composition. Instead, they use intense localized heat to austenitize just the surface layer before quenching.
- Flame Hardening: Uses oxy-fuel torches. Good for large, irregular parts (e.g., large gears, lathe ways).
- Induction Hardening: Uses high-frequency electric coils. Excellent for automation and high-volume shafts. Precise depth control is achieved by adjusting frequency.
Source: Adapted from Google Books & Engineering Standards.



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